Set Guide
Rarest & Most Expensive Cards in Pokemon POP Series 4
Chimecho δ #1 is the most expensive Pokemon POP Series 4 card at about £674.75. The rarest cards are the set's 6 Rares. Released 1 August 2006, the set has 17 cards, ranked below by market price and by printed rarity.
- Chase card
- Chimecho δ #1
- £674.75
- Cards worth £10+
- 12 of 15
- priced cards
- Median card
- £28.41
- per priced card
- Top rarity tiers
- 6 Rare
This page contains eBay Partner Network affiliate links. If you click an eBay link and make a qualifying purchase, we may earn a commission at no extra cost to you.
Top 10 most expensive POP Series 4 cards
Prices as of 31 October 2026.
#1 Most Expensive
Chimecho #1
Rare
A Metal-type card with 60 HP. One listed attack is Wrap.
£674.75
Source: $900.00 from tcgplayer market
Shop this card
#2 Most Expensive
Pikachu #13
Common
A Lightning-type card with 50 HP. One listed attack is Spark (20 damage).
£277.120% since 24 Oct
Source: $369.63 from tcgplayer market
Shop this card
#3 Most Expensive
Deoxys #2
Rare
A Colorless-type card with 70 HP. One listed attack is Crystal Laser (20 damage).
£262.400% since 24 Oct
Source: $350.00 from tcgplayer market
Shop this card
#4 Most Expensive
Pokémon Fan Club #9
Uncommon
Illustrated by Ken Sugimori.
£76.470% since 23 Oct
Source: $102.00 from tcgplayer market
Shop this card
#5 Most Expensive
Mew #4
Rare
A Psychic-type card with 70 HP. One listed attack is Psyshock (20 damage).
£63.73
Source: $85.00 from tcgplayer market
Shop this card
#6 Most Expensive
Squirtle #14
Common
A Water-type card with 50 HP. One listed attack is Tackle (10 damage).
£51.87
Source: $69.19 from tcgplayer market
Shop this card
#7 Most Expensive
Mudkip #11
Common
A Water-type card with 50 HP. One listed attack is Super Hypno Wave (20 damage).
£29.990% since 24 Oct
Source: $40.00 from tcgplayer market
Shop this card
#8 Most Expensive
Grovyle #7
Uncommon
A Grass-type card with 70 HP. One listed attack is Quick Attack (10+ damage).
£28.41
Source: $37.90 from tcgplayer market
Shop this card
#9 Most Expensive
Flygon #3
Rare
A Fighting-type card with 120 HP. One listed attack is Bite (30 damage).
£27.93
Source: $37.25 from tcgplayer market
Shop this card
#10 Most Expensive
Combusken #6
Uncommon
A Fire-type card with 70 HP. One listed attack is Smokescreen (10 damage).
£22.46
Source: $29.96 from tcgplayer market
Shop this card
Top 10 rarest POP Series 4 cards
The highest listed tier in POP Series 4 is Rare, with 6 of the 10 cards in the rarity shortlist. The remaining 4 cards appear across 1 lower printed rarity category. Printed rarity is a checklist category, not a measured pull rate or population count.
Printed rarity labels were captured 31 October 2026.
- #1
Chimecho δ #1Rare
£674.75
- #2
Deoxys δ #2Rare
£262.40
0% since 24 Oct - #3
Mew #4Rare
£63.73
- #4
Flygon #3Rare
£27.93
- #5
Deoxys ex #17Rare
—
- #6
Sceptile #5Rare
—
- #7
Pokémon Fan Club #9Uncommon
£76.47
0% since 23 Oct - #8
Grovyle #7Uncommon
£28.41
- #9
Combusken #6Uncommon
£22.46
- #10
Heal Energy #8Uncommon
£8.69
0% since 24 Oct
What POP Series 4 cards are worth
Chimecho δ is the chase card at about £674.75, roughly 43% of the combined value of the 15 priced cards in the set. 12 cards are worth £10 or more, and the median card is worth about £28.41, so most of a set's value sits in a handful of pulls.
Usable price data is available for 15 of 17 cards in the set checklist. Within the top 10, Chimecho δ is about 30.0 times Combusken, the lowest-priced card shown, when compared in GBP. These are market indicators for a watchlist, not guaranteed sale prices.
How we rank these cards
Price ranking: For each card, we use the first available value in this order: TCGplayer market, mid, then low; if none is available, Cardmarket trend, 7-day average, then 30-day average. We convert USD and EUR values to GBP using the latest daily reference exchange rates before comparing them. Price changes compare our own daily GBP snapshots over the last 30 days.
Rarity ranking: We order the checklist by printed rarity label: Special Illustration Rare, Mega Hyper Rare, Hyper Rare, Secret Rare, Illustration Rare, Ultra Rare, Double Rare, Holo Rare, Ace Spec Rare, Shiny Rare, Trainer Gallery, Gallery Rare, Promo, other Rare, Uncommon, then Common. Cards in the same tier are ordered by market price, highest first. Printed rarity does not measure pull odds, print runs or graded population.
Converted values are comparison estimates; check the marketplace listing for its current price, condition, shipping and availability.